Chemistry · Chapter 16

ΔG°, K and Temperature

One equation ties free energy to the equilibrium constant: ΔG° = −RT ln K. Slide the values and watch K climb or collapse. At the crossover temperature K passes through 1.

log K against temperaturestraight on the 1/T axis

Where K sitseach step is one power of ten

At 298.15 K each 5.71 kJ of ΔG° is worth one step on this ruler. That number is just RT ln 10.

Live numbersR = 8.314 J/mol·K

 K products win
ΔG° at this T 
ΔG° in joules 
RT 
ln K 
log K 
crossover T, where K = 1 

Sliders

Real reactions

Why the line bends
Try the two axes
Against T the plot curves. Against 1000/T it is a straight line, because log K is built from 1/T. Chemists use that straight line to pull ΔH° out of measurements.